THE SYNTHESIS, VIBRATIONAL-SPECTRA, ELECTRONIC-SPECTRA, AND THERMAL-ANALYSIS OF SOME MIXED COMPLEXES WITH PLANAR DITHIOOXAMIDES

被引：6
|
作者：
BELLAIHOU, M
DESSEYN, HO
机构：
[1] Laboratorium voor Anorganische Scheikunde, R.U.C.A, Universiteit Antwerpen, 2020, Antwerpen
来源：
SPECTROSCOPY LETTERS | 1990年 / 23卷 / 10期
关键词：
VIBRATIONAL SPECTRA; COMPLEXES; DITHIOOXAMIDES;
D O I：
10.1080/00387019008054500
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Planar Pd(LH)2 complexes (LH2 = H2NCSCSNH2, CH3HNCSCSNHCH3) form mixed polymeric complexes with Ni(II), Cu(II), Zn(II) and Cd(II) in alcalic media, where the planar Pd(LH)2 complexes act as tetradentates with N-coordination. The electronic spectra and thermal behaviour are discussed, a thorough investigation of the i.r. spectra is presented and special attention has been given to the H/D, CH3/CD3 and Ni-58/Ni-62, Cu-63/Cu-65 and Zn-64/Zn-68 isotopic shifts.
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页码：1253 / 1271
页数：19
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