OXIDATIVE ADDITION OF CHLOROBENZENE ON AN IRON-CYCLOPENTADIENYL CATION TO A LOW-VALENT PALLADIUM COMPLEX

被引：17
|
作者：
AOKI, T
ISHII, Y
MIZOBE, Y
HIDAI, M
机构：
来源：
CHEMISTRY LETTERS | 1991年 / 04期
关键词：
D O I：
10.1246/cl.1991.615
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxidative addition of the coordinated chlorobenzene in [CpFe(C6H5Cl)][PF6] to Pd(PPh3)4 proceeds under THF-reflux conditions to give [CpFe{eta-6-[PdCl(PPh3)2]C6H5}][PF6]. X-ray analysis of this complex revealed that the phenyl ring is sigma-bound to Pd and pi-bound to Fe, and that the palladium center takes the cis-configuration. This complex reacts with CO/MeOH, CO/HNEt2, styrene, and methyl acrylate to give methyl benzoate, N,N-diethylbenzamide, stilbene, and methyl cinnamate, respectively, after photolysis.
引用
收藏
页码：615 / 618
页数：4
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