ANODIC-DISSOLUTION OF ZINC IN AQUEOUS-METHANOLIC TRICHLOROACETIC-ACID SOLUTIONS

被引：5
|
作者：
HEFNY, MM [1 ]
BABAQI, AS [1 ]
ELBASIOUNY, MS [1 ]
ABDULLAH, RM [1 ]
机构：
[1] SANAA UNIV, FAC SCI, DEPT CHEM, YAMEN, U ARAB EMIRATES
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1991年 / 56卷 / 01期
关键词：
D O I：
10.1135/cccc19910236
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Steady state current-potential curves for the anodic dissolution of zinc in aqueous-methanolic 0.25M trichloroacetic acid solutions were constructed for wide ranges of the solution composition and temperature. Analysis of the results reveal that the increase of the water content and rise of temperature of the solution increases the corrosion rate. The most plausible role of the solvent lies within the stabilization of the anodic dissolution reaction products by water molecules. The changes in the properties of the solution due to the presence of methanol which give rise to hindrance of the anodic dissolution reaction are adsorption of methanol, change of viscosity and pH of the solution. These factors seem to be of secondary importance.
引用
收藏
页码：236 / 240
页数：5
相关论文
共 50 条
  • [1] CORROSION AND ANODIC-DISSOLUTION IN METHANOLIC PERCHLORATE SOLUTIONS
    REICH, R
    MALDY, M
    [J]. ELECTROCHIMICA ACTA, 1987, 32 (06) : 983 - 984
  • [2] ANODIC-DISSOLUTION OF METALS .2. ANODIC-DISSOLUTION OF INDIUM IN AQUEOUS PERCHLORATE SOLUTIONS
    SZALMA, J
    FARKAS, J
    KISS, L
    JOO, P
    [J]. ACTA CHIMICA ACADEMIAE SCIENTARIUM HUNGARICAE, 1981, 108 (04): : 413 - 423
  • [3] ANODIC-DISSOLUTION OF METALS .3. MECHANISM OF THE ANODIC-DISSOLUTION OF INDIUM IN AQUEOUS PERCHLORATE SOLUTIONS
    SZALMA, J
    FARKAS, J
    KISS, L
    JOO, P
    SZABO, M
    [J]. MAGYAR KEMIAI FOLYOIRAT, 1983, 89 (08): : 353 - 358
  • [4] ANODIC-DISSOLUTION OF CHROMIUM IN ACID ETHANOL SOLUTIONS
    TSYGANKOVA, LE
    VIGDOROVICH, VI
    [J]. SOVIET ELECTROCHEMISTRY, 1985, 21 (03): : 334 - 337
  • [5] ANODIC-DISSOLUTION OF CADMIUM IN ACID CHLORIDE SOLUTIONS
    ALTUKHOV, VK
    SEDYKH, AS
    TSVETKOVA, TN
    BELOZEROVA, LP
    [J]. PROTECTION OF METALS, 1987, 23 (03): : 356 - 359
  • [6] ADSORPTION AND CORROSION PROPERTIES OF PLATINUM AT HIGH ANODIC POTENTIALS - AQUEOUS-METHANOLIC SOLUTIONS OF PERCHLORIC-ACID
    MIRKIND, LA
    CHEMODANOV, AN
    ASHCHEULOVA, II
    ALBERTINSKII, GL
    KOLOTYRKIN, YM
    [J]. SOVIET ELECTROCHEMISTRY, 1986, 22 (07): : 891 - 897
  • [7] ANODIC-DISSOLUTION OF BERYLLIUM IN NON-AQUEOUS SOLUTIONS
    JOHNSON, JW
    CHEN, SC
    CHANG, JS
    JAMES, WJ
    [J]. CORROSION SCIENCE, 1977, 17 (10) : 813 - 831
  • [8] ANODIC-DISSOLUTION OF NICKEL IN AQUEOUS ETHYLENEGLYCOL SOLUTIONS OF HCL
    TSYGANKOVA, LE
    ZUBREVA, NP
    [J]. JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1978, 51 (10): : 2141 - 2145
  • [9] CONTRIBUTION TO THE KINETICS OF THE ANODIC-DISSOLUTION AND PASSIVITY OF NICKEL IN AQUEOUS ACID-SOLUTIONS
    REAL, SG
    VILCHE, JR
    ARVIA, AJ
    [J]. ANALES DE LA ASOCIACION QUIMICA ARGENTINA, 1979, 67 (04): : 153 - 166
  • [10] THE ANODIC-DISSOLUTION OF COPPER IN HYDROCHLORIC-ACID SOLUTIONS
    CRUNDWELL, FK
    [J]. ELECTROCHIMICA ACTA, 1992, 37 (15) : 2707 - 2714
12345