CALIBRATION OF ANALYTICAL SPECTROMETERS AND METROLOGICAL AIMS OF QUANTITATIVE-ANALYSIS

被引：1
|
作者：
KOTLYAROV, YB
机构：
[1] Independent Mathematical Consultant, London, W8 6LX
来源：
X-RAY SPECTROMETRY | 1990年 / 19卷 / 05期
关键词：
D O I：
10.1002/xrs.1300190504
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The mathematical criteria of calibration, which reflect the metrological aims of quantitative analysis, are formulated. It is shown that the traditionally used calibration procedure is not adequate for these criteria when using the analytical techniques which are required to solve jointly the calibration functions for concentrations in the course of the analysis. A procedure which avoids this shortcoming is proposed. It stipulates the simultaneous construction of the calibration functions and is based on the utilization of a specially introduced metrological index, the ‘indicator of the inaccuracy of a sample analysis’. The paper theory is illustrated by examples in x‐ray fluorescence analysis. Copyright © 1990 John Wiley & Sons, Ltd.
引用
收藏
页码：219 / 225
页数：7
相关论文
共 50 条
12345