COMPLEXES OF SOME 1ST ROW TRANSITION-METAL IONS WITH 2-CYANO-2-HYDROXYIMINOACETYLUREA

被引：1
|
作者：
COSTISOR, O
SAFTA, M
POLICEC, S
机构：
[1] Romanian Academy - Timisoara Branch, Inorganic Chemistry Laboratory, 1900-Timisoara, Bul.Mihai Viteazu
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 06期
关键词：
D O I：
10.1080/00945719408001311
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complex compounds, having the general formula M(CHIAU)2.nH2O have been obtained, where CHIAU denotes 2-cyano-2-hydroxyiminoacetylurea and, for M=Co, Ni, Cu, n=0; M=Mn2+, VO2+, n=1, and M=Fe2+, n=2. The complexes are characterized by means of electrical conductivities, magnetic moments, electronic and IR spectra. It is shown that cobalt, iron, copper and oxovanadium(IV) compounds include a six-membered chelate ring, whereas those of nickel and manganese include a five-membered chelate ring.
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页码：913 / 923
页数：11
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