ACTIVITY-COEFFICIENTS AND GIBBS ENERGIES OF TRANSFER OF HEXAAMMINECOBALT(III) HEXACYANOFERRATE(III)

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作者：

HOLBA, V

HANKOVA, M

机构：

来源：

CHEMICAL PAPERS-CHEMICKE ZVESTI | 1994年 / 48卷 / 05期

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中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solubility of hexaamminecobalt(III) hexacyanoferrate(III) was measured in aqueous and aqueous-methanolic solutions of NaClO4. The experimental mean activity coefficients, evaluated from these measurements are compared with those calculated with the aid of extended Debye-Huckel relations. From their temperature dependence the partial molar enthalpy and partial molar heat capacity have been obtained. The data on solubility in water-methanol mixtures served for the evaluation of Gibbs energies of transfer.

引用

页码：310 / 312

页数：3

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