USE OF ESR FOR CHARACTERIZING EXCHANGE-COUPLED POLYNUCLEAR MU-OXO COMPLEXES OF IRON(III)

被引：1

作者：

SHTEINMAN, AA

机构：

[1] Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Chernogolovka, Moscow Region

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 03期

关键词：

POLYNUCLEAR FE(III) MU-OXO COMPLEXES; ANTIFERROMAGNETIC INTERACTION; ESR;

D O I：

10.1007/BF00698420

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ESR spectra of 13 bi-, tri- and tetranuclear mu-oxo complexes of Fe(III) were studied in the solid state and in solution. On the basis of the data obtained, the broad signal observed near g = 2 for all the complexes was interpreted as resulting from thermal populating of paramagnetic excited states.

引用

页码：421 / 423

页数：3

共 50 条

[1] A MIXED-VALENCE MU-OXO IRON(III)-IRON(II) COMPLEX - A POLYNUCLEAR IRON SODIUM OXO AGGREGATE FROM THE CHEMICAL-REDUCTION OF A MU-OXO DI-IRON(III) COMPLEX
ARENA, F
FLORIANI, C
CHIESIVILLA, A
GUASTINI, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (17) : 1369 - 1371
[2] MAGNETOSTRUCTURAL CORRELATIONS IN MAGNETICALLY COUPLED (MU-OXO)DIIRON(III) COMPLEXES
GORUN, SM
LIPPARD, SJ
[J]. INORGANIC CHEMISTRY, 1991, 30 (07) : 1625 - 1630
[3] THE REACTION OF NITROGEN-OXIDES WITH MU-OXO IRON(III) COMPLEXES
SETTIN, MF
FANNING, JC
KEEFER, LK
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 282 - INOR
[4] REVERSIBLE MU-OXO BRIDGING IN IRON(III)
MOCKLER, GM
BOGE, EM
SIM, PG
SINN, E
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 25 - 25
[5] PHOTODISPROPORTIONATION OF (MU-OXO)BIS[(TETRAPHENYLPORPHINATO)IRON(III)]
RICHMAN, RM
PETERSON, MW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) : 5795 - 5796
[6] REACTION OF CERTAIN NITROGEN-OXIDES WITH IRON(III) PORPHYRIN MU-OXO COMPLEXES
SETTIN, MF
FANNING, JC
[J]. INORGANIC CHEMISTRY, 1988, 27 (08) : 1431 - 1435
[7] SOLUBLE SUBSTITUTED MU-OXO(PHTHALOCYANINATO)IRON(III) DIMERS
DIEING, R
SCHMID, G
WITKE, E
FEUCHT, C
DRESSEN, M
POHMER, J
HANACK, M
[J]. CHEMISCHE BERICHTE, 1995, 128 (06) : 589 - 598
[8] PREPARATION AND CHARACTERIZATION OF THE MU-OXO DIMER AND HYDROXO COMPLEXES OF (TETRAKIS(PENTAFLUOROPHENYL)PORPHINATO)IRON(III)
JAYARAJ, K
GOLD, A
TONEY, GE
HELMS, JH
HATFIELD, WE
[J]. INORGANIC CHEMISTRY, 1986, 25 (19) : 3516 - 3518
[9] (MU-OXO)(MU-CARBOXYLATO)DIIRON(III) COMPLEXES WITH DISTINCT IRON SITES - CONSEQUENCES OF THE INEQUIVALENCE AND ITS RELEVANCE TO DINUCLEAR IRON OXO PROTEINS
NORMAN, RE
YAN, SP
QUE, L
BACKES, G
LING, JS
SANDERSLOEHR, J
ZHANG, JH
OCONNOR, CJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) : 1554 - 1562
[10] A SPECTROPHOTOMETRIC AND ESR STUDY OF MONOMER, MU-OXO DIMER, DI(MU-OXO) DIMER INTERCONVERSION OF NITRIDOTECHNETIUM(VI) COMPLEXES IN SOLUTIONS OF SULFUR AND PHOSPHORUS OXO ACIDS
BALDAS, J
BOAS, JF
IVANOV, Z
JAMES, BD
[J]. INORGANICA CHIMICA ACTA, 1993, 204 (02) : 199 - 212

← 1 2 3 4 5 →