THERMODYNAMIC RESTRICTIONS ON NONISOTHERMAL CHEMICAL-REACTION RATES

被引：5
|
作者：
STROMME, KO
机构：
[1] Department of Chemistry, University of Oslo, N-0315 Oslo 3, P.O. Box 1033, Blindern
来源：
THERMOCHIMICA ACTA | 1990年 / 161卷 / 01期
关键词：
D O I：
10.1016/0040-6031(90)80280-C
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Using arguments derived from classical chemical thermodynamics, it is found that the isobaric, non-isothermal chemical reaction rate is in general a function of heating rate as well as of temperature and composition. However, non-isothermal reaction rate expressions have usually been identified with the corresponding isothermal rate expressions in the literature on non-isothermal chemical reaction kinetics. Generalizing from a specific example, a method is proposed according to which changes in isothermal reaction kinetic expressions may be made to agree with thermodynamics. © 1990.
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页码：1 / 10
页数：10
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