A 5-COORDINATE RUTHENIUM(I) COMPLEX

被引：0

作者：

BIANCHINI, C ^{[1
]}

LASCHI, F ^{[1
]}

PERUZZINI, M ^{[1
]}

ZANELLO, P ^{[1
]}

机构：

[1] CNR, IST STUDIO STEREOCHIM & ENERGET COMPOSTI COOR, I-50132 FLORENCE, ITALY

来源：

GAZZETTA CHIMICA ITALIANA | 1994年 / 124卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The square-pyramidal Ru(I) complex [(PP3)RuCl], 1, has been generated by one-electron reduction of the cationic 16-electron derivative [(PP3)RuCl]BPh(4), 2 [PP3 = P(CH(2)CH(2)PPh(2))(3)]. Compound 1 has been characterized by X-band ESR spectroscopy as well as by an electrochemical investigation. The crystal structure of the square-pyramidal Ru(II) precursor 2 has been determined by an X-ray diffraction analysis.

引用

页码：271 / 274

页数：4

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