HYPERVIRIAL PERTURBATIVE METHOD AND PERIODIC BOUNDARY-CONDITIONS

被引:0
|
作者
FERNANDEZ, FM
CASTRO, EA
机构
来源
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM | 1993年 / 106卷
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暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We apply a perturbation theory without wavefunction, based on a combination of the hypervirial and Hellmann-Feynman theorems, to quantum mechanical models with periodic potentials. In particular we consider periodic solutions to illustrate the treatment of degenerate states. As an illustrative example we consider a problem closely related to the canonical form of the Mathieu equation.
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页码:29 / 33
页数:5
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