Dibromidobis[1-(2-bromobenzyl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)

被引：1
|
作者：
Lu, Chun-Xin [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Xixi Campus, Hangzhou 310028, Zhejiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812021460
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [CuBr2(C14H11BrN4O)(2)], the Cu-II ion is located on an inversion centre and is coordinated by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment. The two carbonyl groups are trans positioned with C=O bond lengths of 1.256 (5) angstrom, in agreement with a classical carbonyl bond. The Cu-O bond length is 2.011 (3) angstrom. The two bromobenzyl rings are approximately parallel to one another, forming a dihedral angle of 70.1 (4)degrees with the coordination plane.
引用
收藏
页码：M785 / +
页数：6
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