SYNTHESIS AND PROPERTIES OF URETHANE ELASTOMER-MODIFIED EPOXY-RESIN HAVING HYDROXYMETHYL GROUP

Synthesis and properties of urethane elastomer-modified epoxy resins were studied. The methane elastomer-modified epoxy resins were synthesized by the reaction of a 4-cresol type epoxy compound having hydroxymethyl groups (EPCDA) with isocyanate prepolymer. The structure was identified by IR, H-1 NMR and GPC. These epoxy resins (EPCDATDI) were mixed with a commercial epoxy resin (DGEBA) in various ratios. The mixed epoxy resins were cured with a mixture of 4,4'-diaminodiphenylmethane and 3-phenylenediamine (molar ratio 6:4) as a hardener. The curing behaviour of these epoxy resins was studied by DSC. The higher the concentration of EPCDATDI, the higher the onset temperature and the smaller the rate constant (k) of the exothermic cure reaction were. It was considered that the ratio of hydroxymethyl group to epoxide group was very small and the molecular weight of EPCDATDI was large. Therefore, the accelerating effect of the hydroxymethyl group on the epoxide-amine reaction was cancelled by the retardant effect of increased molecular weight and viscosity, and decreased molecular motion. Toughness was estimated by Izod impact strength and fracture toughness (K-1C). On addition of 10wt% EPCDATDI with low molecular weight (($) over bar M(n) 6710, estimated by GPC using polystyrene standard samples), Izod impact strength and K-1C increased by 70% and 60%, respectively, compared with unmodified epoxy resin. Glass transition temperatures (T-g) for the cured epoxy resins mixed with EPCDATDI measured by dynamic mechanical spectrometry were the same as those of unmodified epoxy resin. The storage modulus (E') at room temperature decreased with increasing concentration of EPCDATDI. Toughness and dynamic mechanical behaviour of cured epoxy resin systems were studied based on the morphology.