SYNTHESIS AND STRUCTURE OF DINUCLEAR COBALT CLUSTER (C6H5CO2CH2C)(2)Co-2(CO)(6)

被引：0

作者：

You Xiaozeng ^{[1
]}

Meng Qingjin ^{[1
]}

Yang Xinshui ^{[1
]}

Sun Shouheng ^{[1
]}

Bu Xiuren ^{[1
]}

Huang Jinshun ^{[2
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, Nanjing, Peoples R China

[2] Acad Sinica, Fujian Inst Res Struct Matter, Foochow, Fujian, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1988年 / 4卷 / 04期

关键词：

D O I：

10.3866/PKU.WHXB19880421

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cluster (C6H5CO2CH2C)(2)Co-2(CO)(6) has been synthesized and characterized by element analysis, IR, H-1 NMR etc, Its crystal structure has been determined by X-ray diffraction analysis with R = 0.060. The crystal is triclinic, space group Pi with a=8.933(3) angstrom, b=11.830(6) angstrom, c=13.199(3) angstrom., a=65.64(3)degrees, beta=84.55(3)degrees, gamma=72.03(4)degrees, z=2, D-x=1.584g cm(-1) The C C and Co-Co form a tetrahedron with appoximate C-2v symmetry. The Co-Co bond is metl singal bond The hybrid state of carbon atoms in the acetylene is between sp and sp(2).

引用

页码：428 / 431

页数：4

共 7 条

[1] H-1 AND C-13NMR STUDIES OF ACETYLENIC COMPLEXES OF CO2(CO)8
AIME, S
MILONE, L
ROSSETTI, R
STANGHELLINI, PL
[J]. INORGANICA CHIMICA ACTA, 1977, 22 (01) : 135 - 139
[2] AREGODA M, 1983, J AM CHEM SOC, V105, P1863
[3] Cetini G, 1967, J ORGANOMET CHEM, V8, P149
[4] Dickson R. S., 1974, ADV ORGANOMET CHEM, V12, P323, DOI DOI 10.1016/S0065-3055(08)60454-2
[5] THE X-RAY SINGLE-CRYSTAL AND MOLECULAR-STRUCTURES OF "(CO2(CO)6C2PH(I),CO2ME(II)(292-K)2) AND (CO2(CO)6C2BUT(III)(200-K)2)
GREGSON, D
HOWARD, JAK
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (AUG) : 1024 - 1027
[6] JOHNSON AW, 1948, J CHEM SOC, P1009
[7] LAIDLER KJ, 1954, CATALYSIS, V1, pCH5

← 1 →