SYNTHETIC NONCYCLIC IONOPHORES WITH MULTIPLE CARBOXYLATE GROUPS FOR ALKALINE-EARTH METAL-CATIONS

被引：5
|
作者：
NAKATSUJI, Y
MATSUMOTO, M
MASUYAMA, A
KIDA, T
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, 565, 2-1, Yamada-oka
来源：
JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1994年 / 18卷 / 04期
关键词：
SYNTHETIC IONOPHORE; LIPOPHILIC QUINALDIC ACID; ALKALINE EARTH METAL TRANSPORT; LIQUID MEMBRANE;
D O I：
10.1007/BF00707386
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of synthetic ionophores containing two carboxylic acid groups were synthesized as carriers for alkaline earth metal cations. Among them, the lipophilic derivative having a trimethylene bridge and multiple quinaldate moieties selectively transported barium ion from the basic aqueous phase to the acidic aqueous phase through the bulk dichloromethane liquid membrane. The cation selectivity was explained by considering the fit of the cation diameter with the pseudocyclic cavity.
引用
收藏
页码：377 / 383
页数：7
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