ELECTROLYSIS OF EMULSIONS OF ORGANIC-COMPOUNDS ON HYDROPHOBIC ELECTRODES

被引：20

作者：

KUNUGI, Y ^{[1
]}

CHEN, PC ^{[1
]}

NONAKA, T ^{[1
]}

CHONG, YB ^{[1
]}

WATANABE, N ^{[1
]}

机构：

[1] APPL SCI RES INST,SAKYO KU,KYOTO 606,JAPAN

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1993年 / 140卷 / 10期

关键词：

D O I：

10.1149/1.2220918

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Suspensions of some water-insoluble organic compounds, such as alcohols, amines, activated olefines, and dibromobenzene, were electrolyzed efficiently on a hydrophobic electrode prepared by composite-plating nickel with tetrafluoroethylene oligomer (TFEO) particles. This result suggests a useful method for suspension electrolysis from a practical aspect and a hypothesis (organic droplet-collecting effect) that the hydrophobic electrode surface is covered by thin films of the organic compounds and consequently the electrolysis of water (oxygen and hydrogen evolution) is suppressed.

引用

页码：2833 / 2836

页数：4

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