Poly[[aqua(mu 2-4,4'-bipyridine-kappa N-2:N')[mu(3)-3-bromo-2-(carboxylatomethyl)benzoato-kappa O-3(1):O-1':O-2]cadmium] monohydrate]

被引：0
|
作者：
Liu, Yangmei [1 ,2 ]
Cao, Kai [1 ]
Wang, Fenglin [1 ]
机构：
[1] Jiangsu Prov Supervising & Testing Res Inst Prod, Natl Food Packaging Prod Qual Supervis & Inspect, Nanjing 210007, Jiangsu, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 12.4; mean σ(C-C) = 0.011 Å; R factor = 0.049; single-crystal X-ray study; T = 291 K; wR factor = 0.118;
D O I：
10.1107/S1600536812031297
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, {[Cd(C9H5BrO4)(C10H8N2)(H2O)] . H2O} n, the Cd II atom has a distorted octahedral coordination geometry. Two N atoms from two 4,40-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxylate O atoms from three 3-bromo-2-(carboxylatomethyl) benzoate (bcb) ligands and one O atom from a water molecule. The bipy and bcb ligands link the Cd II atoms into a three-dimensional network. O-H ... O hydrogen bonds and pi-pi interactions between the pyridine and benzene rings [centroid-centroid distance = 3.736 (4)angstrom] are present in the crystal.
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页码：M1071 / +
页数：9
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