CRYSTAL-STRUCTURE OF THE 1ST PALLADIUM AMMINE MOLYBDATE - PD(NH3)4(MOO4)

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作者：
LALIGANT, Y
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来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1993年 / 30卷 / 10期
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O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Pd(NH3)4(MoO4) is tetragonal (space group I4(1)/amd, Z = 4) with a = 7.4618(4)angstrom and c = 15.5565(10)angstrom. The structure was refined from single crystal X-ray diffraction data using 231 independent X-ray reflections to R(W) = 0.020 (R = 0.020). The crystal structure of Pd(NH3)4(MoO4) is built up by isolated PdN4 square planes and MoO4 tetrahedra. Hydrogen atoms were located around nitrogen and ensure the three dimensional cohesion of the structure by N-H.....O bonding.
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页码：1017 / 1023
页数：7
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