X-RAY STRUCTURAL STUDY OF HALOGENCHALCOGENITE GOLD(III) COMPLEXES

被引：0

作者：

RYBAKOV, VB ^{[1
]}

ASLANOV, LA ^{[1
]}

TIMOSHCHENKO, NI ^{[1
]}

VOLKOV, SV ^{[1
]}

FOKINA, ZA ^{[1
]}

PEKHNYO, VI ^{[1
]}

机构：

[1] ACAD SCI UKSSR,INST GEN & INORGAN CHEM,KIEV,UKRAINE,USSR

来源：

UKRAINSKII KHIMICHESKII ZHURNAL | 1992年 / 58卷 / 05期

关键词：

Crystals - Molecular Structure - Sulfur Compounds - X-Ray Analysis;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-ray structural study of the compounds AuX3(YZ4) where Y is S, Se or Te; X and Z are Cl or Br, has been carried out. Unit cell parameters, atom positions, interatomic distances and valence angles for four compounds are given in the paper. It have been shown that the gold atom in the molecule is surrounded by four halogen atoms which are situated in the vertices of a slightly distorted square. Chalcogen atom is in the vertex of a trigonal pyramid, base of which is formed by halogen atoms. Non-valent contacts of Y and X atoms have been observed. It has been shown that complexes containing Cl and Br, S and Se have similar crystal structure; introduction of Te, however, leads the change of the structural type.

引用

页码：359 / 363

页数：5

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