KINETIC RESOLUTION OF RACEMIC CARBOXYLIC-ACIDS AND ALCOHOLS WITH HOMOCHIRAL ALCOHOLS AND CARBOXYLIC-ACIDS, RESPECTIVELY, AND THE MUKAIYAMA OR PALOMO REAGENTS

被引：30
|
作者：
MAZON, A
NAJERA, C
YUS, M
HEUMANN, A
机构：
[1] UNIV ALICANTE,DEPT QUIM ORGAN,APDO 99,E-03080 ALICANTE,SPAIN
[2] UNIV AIX MARSEILLE,CTR ST JEROME,ENSSPICAM,URA 1410,F-13013 MARSEILLE,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 11期
关键词：
D O I：
10.1016/0957-4166(92)80022-O
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Mukaiyama and Palomo reagents have been used for the kinetic resolution of racemic carboxylic acids or alcohols with homochiral alcohols or carboxylic acids, respectively, in the presence of triethylamine. Thus, enantiomerically enriched carboxylic acids (e.e.<68%), alcohols (e.e.<41%) or diastereoisomerically enriched esters (d.e.<84%) are obtained.
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页码：1455 / 1466
页数：12
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