DIRECT OBSERVATION OF PHOTOINDUCED CHARGE SEPARATION DYNAMICS IN SOLID POLY(N-VINYLCARBAZOLE) POWDERS BY DIFFUSE REFLECTANCE LASER PHOTOLYSIS

被引:6
|
作者
KOSHIOKA, M [1 ]
IKEDA, N [1 ]
ITAYA, A [1 ]
MASUHARA, H [1 ]
机构
[1] KYOTO INST TECHNOL, DEPT POLYMER SCI & ENGN, MATSUGASAKI, KYOTO 606, JAPAN
关键词
D O I
10.1246/cl.1992.1165
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transient absorption spectra of poly(N-vinylcarbazole) powders doped with some electron acceptors are composed of the bands of acceptor anion and carbazole cation, indicating directly charge separation from the excited state. Electronic structure and decay processes of polymer cation are considered and compared with transparent film.
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页码:1165 / 1168
页数:4
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