THE OXIDATION OF ORTHO-ANISIDINE IN ALKALINE-MEDIUM - A PRODUCT CHARACTERIZATION AND AN EPR STUDY

被引：1
|
作者：
BOLOGNESE, A
BUONANNO, M
CANTILENA, A
MUSCI, G
ALBERTI, A
机构：
[1] UNIV ROMA LA SAPIENZA,CNR,CTR BIOL MOLEC,DIPARTIMENTO SCI BIOMED,I-00185 ROME,ITALY
[2] CNR,ICOCEA,I-40064 OZZANO EMILIA,ITALY
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1994年 / 72卷 / 05期
关键词：
D O I：
10.1139/v94-168
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkaline oxidation of ortho-anisidine by potassium ferricyanide in alkaline aqueous solution was examined. Azo compounds, a diamine, and para-iminoquinones were isolated from the highly coloured reaction mixture. The reaction was also carried out within the cavity of an EPR spectrometer and two radical species have been detected. Following these product results and EPR studies, a radical mechanism is proposed for the process.
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收藏
页码：1351 / 1356
页数：6
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