ACID-BASE PROPERTIES OF ALPO-5 MOLECULAR-SIEVES MODIFIED BY NICKEL AND MOLYBDENUM

被引：0
|
作者：
KALVACHEV, Y
SPOJAKINA, A
KOSTOVA, N
DIMITROV, L
机构：
来源：
ACID-BASE CATALYSIS II | 1994年 / 90卷
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The decomposition of 2-propanol has been chosen as a test reaction to study the acid-base character of ALPO-5 molecular sieves modified by nickel and molybdenum. It was found that the type of the active components as well as the mode of their introduction affect acid-base properties of catalysts. Arguments for formation of heteropolymolybdate structures on the molecular sieve surface have been adduced. The role of different fragments in the structure of the modified molecular sieves has been discussed in connection with acidity and basicity of the catalysts.
引用
收藏
页码：413 / 418
页数：6
相关论文
共 50 条
  • [1] ELEMENTARY STEPS OF ACID-BASE CATALYZED-REACTIONS IN MOLECULAR-SIEVES
    LERCHER, JA
    MIRTH, G
    STOCKENHUBER, M
    NARBESHUBER, T
    KOGELBAUER, A
    ACID-BASE CATALYSIS II, 1994, 90 : 147 - 156
  • [2] Praseodymium Incorporated AlPO-5 Molecular Sieves for Aerobic Oxidation of Ethylbenzene
    Sundaravel, B.
    Babu, C. M.
    Palanisamy, B.
    Palanichamy, M.
    Shanthi, K.
    Murugesan, V.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2013, 13 (04) : 2507 - 2516
  • [3] ALPO4 MOLECULAR-SIEVES MODIFIED WITH METAL CHELATE COMPLEXES
    KOWALAK, S
    BALKUS, KJ
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1992, 57 (04) : 774 - 780
  • [4] SYNTHESIS OF CO AND V-CONTAINING ALPO4-5 MOLECULAR-SIEVES AND CHARACTERIZATION OF THEIR ACID PROPERTIES
    MARTIN, A
    BERNDT, H
    LOHSE, U
    LUCKE, B
    REACTION KINETICS AND CATALYSIS LETTERS, 1995, 56 (01): : 37 - 46
  • [5] NITROGEN INCORPORATION IN ALPO4-5 MOLECULAR-SIEVES BY THERMAL AMMONOLYSIS
    STEIN, A
    WEHRLE, B
    JANSEN, M
    ZEOLITES, 1993, 13 (04): : 291 - 298
  • [6] SYNTHESIS AND CATALYTIC PROPERTIES OF SUBSTITUTED ALPO4-31 MOLECULAR-SIEVES
    ZUBOWA, HL
    RICHTER, M
    ROOST, U
    PARLITZ, B
    FRICKE, R
    CATALYSIS LETTERS, 1993, 19 (01) : 67 - 79
  • [7] Nitric acid free cyclohexane to adipic acid production using nickel and vanadium incorporated AlPO-5 molecular sieve
    Prabu, Marimuthu
    Sharma, Shweta
    Raja, Abhishekram
    Archana, Ramakrishnan
    Samruddhi, Mane
    Raja, Thirumalaiswamy
    MOLECULAR CATALYSIS, 2023, 540
  • [8] ACIDITY OF SILICON MODIFIED COAPO-5 MOLECULAR-SIEVES
    BORADE, RB
    CLEARFIELD, A
    APPLIED CATALYSIS A-GENERAL, 1992, 80 (01) : 59 - 77
  • [9] TREATMENTS OF ALPO4-5 AND SAPO-5 MOLECULAR-SIEVES WITH SILICON TETRACHLORIDE VAPOR
    LI, HX
    DAVIS, ME
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (01): : 331 - 334
  • [10] RAMAN-SPECTRA OF THE UNIDIMENSIONAL ALUMINOPHOSPHATE MOLECULAR-SIEVES ALPO(4)-11, ALPO(4)-5, ALPO(4)-8, AND VPI-5
    HOLMES, AJ
    KIRKBY, SJ
    OZIN, GA
    YOUNG, D
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (17): : 4677 - 4682
12345