Synthesis and Physicochemical Properties of Branched Solid Polymer Electrolytes Containing Ethylene Carbonate Group

被引：1
|
作者：
Kim, Doo-Hwan [1 ]
Ryu, Sang-Woog [1 ]
机构：
[1] Chungbuk Natl Univ, Dept Chem Engn, Cheongju 361763, Chungbuk, South Korea
来源：
JOURNAL OF THE KOREAN ELECTROCHEMICAL SOCIETY | 2015年 / 18卷 / 04期
关键词：
Ethylene carbonate; Polymer electrolyte; Branch; Ionic conductivity; Electrochemical stability;
D O I：
10.5229/JKES.2015.18.4.150
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In this study polymer electrolytes containing ethylene carbonate group which have a high dielectric constant and poly(ethylene glycol) as branches were prepared by the Williamson reaction between poly(ethylene glycol) methyl ether and block copolymers composed of glycerol-1,2-carbonate and 4-chloromethyl styrene. Interestingly, the highest ionic conductivity of 1.75 x 10(-5) S cm(-1) was observed from the polymer electrolyte having 7 mol% of ethylene carbonate and the [ EO]:[ Li] ratio of 32: 1. Moreover, it was found that the electrochemical stability of polymer electrolyte was achieved up to 5.5 V because of the presence of ethylene carbonate.
引用
收藏
页码：150 / 155
页数：6
相关论文
共 50 条
  • [1] Effect of ethylene carbonate on properties of PVP-CsAlO2-LiClO4solid polymer electrolytes
    Saeed, Adel Morshed Nagi
    Hezam, Abdo
    Al-Gunaid, Murad Q. A.
    Somesh, T. E.
    Siddaramaiah
    POLYMER-PLASTICS TECHNOLOGY AND MATERIALS, 2021, 60 (02): : 132 - 146
  • [2] Synthesis and Properties of Polycarbosilanes Having 5-Membered Cyclic Carbonate Groups as Solid Polymer Electrolytes
    Matsumoto, Kozo
    Kakehashi, Miho
    Ouchi, Hirotaka
    Yuasa, Masayoshi
    Endo, Takeshi
    MACROMOLECULES, 2016, 49 (24) : 9441 - 9448
  • [3] Theoretical Study of the Electrochemical Properties for Solid Electrolytes Containing Ethoxy and Carbonate Groups
    Zhao, Yuehua
    Wang, Zirun
    Zhao, Siying
    Pan, Xiumei
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2022, 169 (08)
  • [4] Synthesis and characterization of amorphous poly(ethylene oxide)/poly(trimethylene carbonate) polymer blend electrolytes
    Rodrigues, L. C.
    Silva, M. M.
    Smith, M. J.
    ELECTROCHIMICA ACTA, 2012, 86 : 339 - 345
  • [5] Effect of ethylene carbonate on the ionic conduction in poly(vinylidenefluoride-hexafluoropropylene) based solid polymer electrolytes
    Ramesh, S.
    Ling, Ong Poh
    POLYMER CHEMISTRY, 2010, 1 (05) : 702 - 707
  • [6] Synthesis and Properties of Poly-Ether/Ethylene Carbonate Electrolytes with High Oxidative Stability
    Khan, Kasim
    Tu, Zhengyuan
    Zhao, Qing
    Zhao, Chenzi
    Archer, Lynden A.
    CHEMISTRY OF MATERIALS, 2019, 31 (20) : 8466 - 8472
  • [7] Synthesis and characterization of poly(ethylene oxide-co-ethylene carbonate) macromonomers and their use in the preparation of crosslinked polymer electrolytes
    Elmér, AM
    Jannasch, P
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (07) : 2195 - 2205
  • [8] Solid polymer electrolytes based on ethylene oxide polymers
    Florjanczyk, Zbigniew
    Zygadlo-Monikowska, Ewa
    Ostrowska, Justyna
    Frydrych, Anita
    POLIMERY, 2014, 59 (01) : 80 - 87
  • [9] SYNTHESIS, CHARACTERIZATION AND ELECTRICAL-PROPERTIES OF THE NOVEL POLYMER ELECTROLYTES BASED ON POLYESTERS CONTAINING ETHYLENE-OXIDE MOIETY
    KIM, DW
    SONG, JS
    PARK, JK
    ELECTROCHIMICA ACTA, 1995, 40 (11) : 1697 - 1700
  • [10] Synthesis and properties of aromatic polyethers containing poly(ethylene oxide) side chains as polymer electrolytes for lithium ion batteries
    Voege, Andrea
    Deimede, Valadoula
    Paloukis, Fotis
    Neophytides, Stylianos G.
    Kallitsis, Joannis K.
    MATERIALS CHEMISTRY AND PHYSICS, 2014, 148 (1-2) : 57 - 66
12345