ARF-STAR, KRF-STAR AND XEF-STAR EMISSIONS PRODUCED FROM DISSOCIATIVE ION RECOMBINATION REACTIONS OF AR+, KR+ AND XE+ WITH SF-6(-) IN THE FLOWING AFTERGLOW

被引：25

作者：

TSUJI, M ^{[1
]}

FURUSAWA, M ^{[1
]}

NISHIMURA, Y ^{[1
]}

机构：

[1] KYUSHU UNIV,GRAD SCH ENGN SCI,DEPT MOLEC SCI & TECHNOL,KASUGA,FUKUOKA 816,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 166卷 / 04期

关键词：

D O I：

10.1016/0009-2614(90)85044-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ArF*, KrF*, and XeF* emissions resulting from dissociative ion recombination between rare gas cations and SF6- anions have been studied in the flowing afterglow. The anions were formed by thermal electron capture by SF6. The KrF* product state distribution from the two Kr+(2P 3 2, 1 2) spin-orbit states showed that the B and C states are preferentially formed by the Kr+(2P 3 2) reaction, while Kr+(2P 1 2) favors formation of the D state. The state selectivity can be explained by consideration of the potential energy diagram. © 1990.

引用

页码：363 / 368

页数：6

共 2 条

[1] SPIN ORBIT STATE SELECTIVITY IN KRF-STAR AND XEF-STAR FORMATION FROM ION-RECOMBINATION REACTIONS OF KR+(2P3/2,1/2) AND XE+(2P3/2,1/2) WITH SF6- IN THE FLOWING AFTERGLOW
TSUJI, M
FURUSAWA, M
NISHIMURA, Y
JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (11): : 6502 - 6503
[2] VIBRATIONAL DISTRIBUTIONS OF KRF(B) AND XECL(B) PRODUCED FROM IONIC-RECOMBINATION REACTIONS OF KR+(P-2(3/2))+SF6- AND XE+(P-2(3/2))+CL-+HE
TSUJI, M
MURAOKA, T
IDE, M
UJITA, H
NISHIMURA, Y
OBASE, H
JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (04): : 2880 - 2886

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