Tris(2,6-dibenzoyl-4-methylphenolato-kappa O-2(1),O-2)cobalt(III)

被引：0
|
作者：
Gupta, Abhishek K. [1 ]
Srivastava, Sanjay [1 ]
Butcher, Ray J. [2 ]
机构：
[1] Maulana Azad Natl Inst Technol, Dept Mat Sci & Met Engn, Bhopal 462051, India
[2] Howard Univ, Dept Chem, 525 Coll St NW, Washington, DC 20059 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
data-to-parameter ratio = 15.3; mean σ(C-C) = 0.004 Å; R factor = 0.055; single-crystal X-ray study; T = 123 K; wR factor = 0.154;
D O I：
10.1107/S1600536814001664
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(C21H15O3)(3)], the Co-III ion is coordinated in a slightly distorted octahedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methylphenolate ligands. The dihedral angles between the mean planes of the central phenolate rings and the peripheral phenyl rings are 46.62 (10)/87.06 (9), 60.44 (8)/23.13 (8) and 46.49 (6)/65.29 (6)degrees. The crystal packing is stabilized by weak intermolecular C-H center dot center dot center dot O interactions. Molecules are further linked by two pi-pi [centroid-centroid distances = 3.8612 (14) and 3.9479 (14) angstrom] and four C-H center dot center dot center dot pi interactions, forming a three-dimensional network.
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页码：M67 / +
页数：16
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