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STUDIES OF CONFORMATION AND ELECTRONIC-STRUCTURE OF THE RADICAL CATIONS OF 2,4-DI(N-CARBAZOLYL)PENTANE AND 1,3-DINAPHTHYLPROPANES IN FLUIDS AND IN RIGID MATRICES BY OPTICAL SPECTROSCOPY AND MOLECULAR-ORBITAL ANALYSES
被引：21
|作者：
TSUJII, Y
TSUCHIDA, A
YAMAMOTO, M
MOMOSE, T
SHIDA, T
机构：
[1] KYOTO UNIV,FAC ENGN,DEPT POLYMER CHEM,SAKYO KU,KYOTO 606,JAPAN
[2] KYOTO UNIV,FAC SCI,DEPT CHEM,KYOTO 606,JAPAN
来源：
关键词：
D O I：
10.1021/j100175a041
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ;
081704 ;
摘要：
Conclusions of the previous studies of the systems in the title from laser photolysis and kinetic analyses are confirmed by comparing optical spectra observed for laser-photolyzed solutions at a room temperature with those for radiolyzed frozen solutions. The experimental results are consistent with the computational results of geometry and electronic transition.
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页码：8635 / 8640
页数：6
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