SYNTHESIS, REACTIONS, AND C-13 FT NMR-SPECTROSCOPY OF POLYMER-BOUND STEROIDS

被引：29

作者：

BLOSSEY, EC ^{[1
]}

CANNON, RG ^{[1
]}

FORD, WT ^{[1
]}

PERIYASAMY, M ^{[1
]}

MOHANRAJ, S ^{[1
]}

机构：

[1] OKLAHOMA STATE UNIV,DEPT CHEM,STILLWATER,OK 74078

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 15期

关键词：

D O I：

10.1021/jo00302a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dehydrocholic acid (3,7,12-trioxo-β-cholanoic acid) and cholic acid (3α,7α,12α-trihydroxy-5β-cholanoic acid) were attached, via their carboxyl groups, to chloromethylated poly(styrene-2% divinylbenzene) to form the polymers 1 and 6, respectively. Synthetic transformations of the bound steroids containing the carbonyl and hydroxyl groups and esterification of hydroxyl functions was obtained by 13C NMR spectra of solvent swollen polymer gels. The 13C NMR spectra of the bound steroids represents a major advance in the analysis of polymer-supported species, permitting structural assignments to be made, on a qualitative basis, of the intact polymer without resorting to cleavage reactions of the bound material. © 1990, American Chemical Society. All rights reserved.

引用

页码：4664 / 4668

页数：5

共 50 条

[1] SYNTHESIS, REACTIONS AND C-13 PFT-NMR SPECTROSCOPY OF POLYMER-BOUND STEROIDS
BLOSSEY, EC
FORD, WT
PERIYASAMY, M
MOHANRAJ, S
CANNON, RG
REACTIVE POLYMERS, 1987, 6 (2-3): : 334 - 334
[2] SYNTHESIS, REACTIONS AND C-13 PFT-NMR SPECTROSCOPY OF POLYMER-BOUND STEROIDS.
Blossey, Erich C.
Ford, Warren T.
Periyasamy, Mookkan
Mohanraj, S.
Cannon, Randall G.
Reactive polymers. Ion exchangers, sorbents, 1986, 6 (2-3):
[3] SYNTHESIS, REACTIONS AND C-13-PFT-NMR SPECTROSCOPY OF POLYMER-BOUND STEROIDS
BLOSSEY, EC
FORD, WT
PERIYASAMY, M
MOHANRAJ, S
CANNON, RG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 55 - ORGN
[4] RAPID SCAN C-13 FT NMR-SPECTROSCOPY
REYNOLDS, GF
SCHIMMELMAN, MK
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1978, 175 (MAR): : 8 - 8
[5] MONITORING ELECTROCHEMICAL REACTIONS BY C-13 NMR-SPECTROSCOPY
ALBERT, K
DREHER, EL
STRAUB, H
RIEKER, A
MAGNETIC RESONANCE IN CHEMISTRY, 1987, 25 (10) : 919 - 922
[6] CYANOHYDRIN SYNTHESIS - STUDIES BY C-13 NMR-SPECTROSCOPY
SERIANNI, AS
NUNEZ, HA
BARKER, R
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (SEP): : 63 - 63
[7] SYNTHESIS AND C-13 FT NMR-SPECTROSCOPY OF FURAN-2,3-DIONE DERIVATIVES
HNACH, M
AYCARD, JP
ZINEDDINE, H
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1991, (03): : 393 - 396
[8] C-13 NMR-SPECTROSCOPY OF OXEPINS
BERGER, S
RIEKER, A
ORGANIC MAGNETIC RESONANCE, 1974, 6 (02): : 78 - 84
[9] C-13 NMR-SPECTROSCOPY OF NOSIHEPTIDE
DEPAIRE, H
THOMAS, JP
BRUN, A
OLESKER, A
LUKACS, G
TETRAHEDRON LETTERS, 1977, (16) : 1397 - 1400
[10] C-13 NMR-SPECTROSCOPY OF NEOLIGNANS
WENKERT, E
GOTTLIEB, HE
GOTTLIEB, OR
PEREIRA, MODS
FORMIGA, MD
PHYTOCHEMISTRY, 1976, 15 (10) : 1547 - 1551

← 1 2 3 4 5 →