STRUCTURE OF CARBON-TETRACHLORIDE PLUS T-BUTANOL MIXTURES FROM POSITRON-ANNIHILATION AND ULTRASONIC VELOCITY-MEASUREMENTS

被引:2
|
作者
JERIE, K [1 ]
BARANOWSKI, A [1 ]
GLINSKI, J [1 ]
机构
[1] UNIV WROCLAW,INST CHEM,PL-50383 WROCLAW,POLAND
关键词
D O I
10.12693/APhysPolA.83.313
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The densities of and sound velocities in t-butyl alcohol solutions in CCl4 were determined in temperature range 25 to 45-degrees-C. From these data the adiabatic compressibility coefficients of the solutions were calculated, as well as excess densities and compressibilities. The positron annihilation spectrum for this system in room temperature was measured. The results plotted against alcohol concentration suggest that the structural processes occurring in this system are caused by dimerization of the solute molecules.
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页码:313 / 320
页数:8
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