[3+2] CYCLOADDITIONS OF ALLYLSILANES .2. A VERSATILE AND EFFICIENT SYNTHESIS OF ANNULATED CYCLOPENTANES BY STEREOSELECTIVE [3+2] CYCLOADDITION OF ALLYLSILANES AND CYCLOALKENYL METHYL KETONES

被引：89

作者：

KNOLKER, HJ ^{[1
]}

FOITZIK, N ^{[1
]}

GOESMANN, H ^{[1
]}

GRAF, R ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST ANORGAN CHEM,W-7500 KARLSRUHE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310811

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Useful precursors for cyclopentanoid natural products and for compounds with medium-sized rings can be PrePared by the title reaction (a). This new annulation reaction is postulated to involve a cationic 1,2-silyl shift proceeding via a pentavalent silicon center.

引用

页码：1081 / 1083

页数：3

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