INVESTIGATIONS INTO THE FREE-RADICAL POLYMERIZATIONS OF ALLYL CARBONATES .1. THE REACTION OF T-BUTOXYL RADICAL

被引：7

作者：

QURESHI, A

SOLOMON, DH

KELLY, DP

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

[2] LA TROBE UNIV,FAC SCI & TECHNOL,BUNDOORA,VIC 3083,AUSTRALIA

来源：

EUROPEAN POLYMER JOURNAL | 1995年 / 31卷 / 09期

关键词：

D O I：

10.1016/0014-3057(95)00036-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical trapping technique employing 1,1,3,3-tetramethylisoindolinyl-2-oxyl (TMIO) as scavenger has been used to study the reactions of t-butoxyl radicals with diethylene glycol bis (allyl carbonate) [CR39] and some model compounds. Extensive hydrogen abstraction as well as attack at the allyl group was observed. Interestingly, abstraction from methoxy ethyl allyl carbonate, ethoxy ethyl allyl carbonate and CR39 occurred predominantly from the ethylene groups of the glycol moiety.

引用

页码：809 / 818

页数：10

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