THE INVENTION OF RADICAL REACTIONS .21. SIMPLE METHODS FOR THE RADICAL DEOXYGENATION OF PRIMARY ALCOHOLS

被引：57

作者：

BARTON, DHR ^{[1
]}

BLUNDELL, P ^{[1
]}

DORCHAK, J ^{[1
]}

JANG, DO ^{[1
]}

JASZBERENYI, JC ^{[1
]}

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843

来源：

TETRAHEDRON | 1991年 / 47卷 / 43期

关键词：

THIONOCARBONATES; TRIBUTYLTIN HYDRIDE; TRIPHENYLSILANE; DIPHENYLSILANE; PHENYLSILANE; RADICAL DEOXYGENATIONS;

D O I：

10.1016/S0040-4020(01)86502-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel radical-chain deoxygenations of primary alcohols are described. The alcohols are acylated with the reagents pentafluorophenyl chlorothionoformate, 2,4,6-trichlorophenyl chlorothionoformate and 4-fluorophenyl chlorothionoformate and the intermediate thionocarbonates are deoxygenated with tributyltin hydride, triphenylsilane, diphenylsilane or phenylsilane in high-yielding reactions.

引用

页码：8969 / 8984

页数：16

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