SYNTHESIS AND CHARACTERIZATION OF A PALLADIUM-OSMIUM MIXED-METAL CLUSTER - CRYSTAL-STRUCTURE OF [OS6PD(CO)18(BIPY)]CENTER-DOT-CHCL3 (BIPY = 2,2'-BIPYRIDINE)

被引：15

作者：

CHAN, S ^{[1
]}

WONG, WT ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,POKFULAM RD,HONG KONG,HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 10期

关键词：

D O I：

10.1039/dt9940001605

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2'-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy) (CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.

引用

页码：1605 / 1606

页数：2

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