PRODUCTION OF PHOSPHORIC-ACID WITH LOW CONTENT OF IMPURITIES

The present work is to study the possibility for controlled distribution of the impurities when they are decomposed by sulphuric acid to wet phosphoric acid and phosphogypsum, as well as generating technological conditions for production of clean wet phosphoric acid and its derivatives - phosphoric fertilizers, food phosphates and other phosphoric products. A coefficient of distribution D-A is introduced as a general criterion for elements dispersion. The study includes relationships between the weight ratio sulphuric acid/natural phosphate and D-A; the period of decomposition and D-A; the particle's size content of the natural phosphate and D-A The obtained experimental data and relationships about the influence of the above discussed technological parameters on dispersion of more than 23 elements allow for control of that process in wet phosphoric acid and phosphogypsum by selecting specific technological conditions. Thus, depending on the requirements of acid's consumers and procedures for secondary processing of phosphogypsum to end-products, a selective decomposition of the natural phosphates to phosphoric acid and phosphogypsum can be carried out with content of the impurities in those products varying in narrow limits.