THE EQUATION OF STATE APPROACH FOR INTERFACIAL-TENSIONS - COMMENTS

被引:34
|
作者
LI, D [1 ]
MOY, E [1 ]
NEUMANN, AW [1 ]
机构
[1] UNIV TORONTO,DEPT MECH ENGN,5 KINGS COLL RD,TORONTO M5S 1A4,ONTARIO,CANADA
关键词
D O I
10.1021/la00094a032
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In a recent publication,1 Johnson and Dettre attempted to criticize the equation of state approach for interfacial tensions. Their main point, in our understanding, is of a dual nature, as follows: the number of degrees of freedom for a two-component three-phase system is supposed to be one, contrary to our contention that it is two for a two-component solid-liquid-vapor system; there is, within this concept, no difference between a solid-liquidvapor system and a liquid-liquid-vapor system. Both assertions are false, as we shall show below. © 1990, American Chemical Society. All rights reserved.
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页码:885 / 888
页数:4
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