ION-PAIR REVERSED-PHASE LIQUID-CHROMATOGRAPHY WITH FLUOROMETRIC DETECTION OF PESTICIDES

被引：9
|
作者：
SANCHEZ, FG
DIAZ, AN
PAREJA, AG
机构：
[1] Departamento de Química Analítica, Facultad de Ciencias, Universidad de Málaga
来源：
JOURNAL OF CHROMATOGRAPHY A | 1994年 / 676卷 / 02期
关键词：
D O I：
10.1016/0021-9673(94)80435-4
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
The pesticides asulam, propoxur, coumatetralyl, biphenyl-2-ol and thiabendazole were separated by ion-pair reversed-phase liquid chromatography with fluorescent detection. The mobile phase contained methanol, acetic acid and sodium cholate as ion-pair reagent. In addition, tetramethylammonium hydrogensulphate and triethylamine were added to elute the pesticides. Separations were accomplished in less than 20 min. Interferences from nineteen pesticides were studied and recoveries from synthetic mixtures ranging from 90 to 110%. Recoveries from spiked apples and wheat grains ranged from 94 to 105% with relative standard deviations between 1.4 and 9.2% and detection limits between 0.1 and 1.9 ng.
引用
收藏
页码：347 / 354
页数：8
相关论文
共 50 条
  • [1] REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY OF TETRACYCLINES
    EKSBORG, S
    EKQVIST, B
    [J]. JOURNAL OF CHROMATOGRAPHY, 1981, 209 (02): : 161 - 173
  • [2] REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY OF THE ANGIOTENSINS
    PATEL, HB
    STOBAUGH, JF
    RILEY, CM
    [J]. JOURNAL OF CHROMATOGRAPHY, 1991, 536 (1-2): : 357 - 370
  • [3] RETENTION MECHANISM FOR REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY
    BIDLINGMEYER, BA
    DEMING, SN
    PRICE, WP
    SACHOK, B
    PETRUSEK, M
    [J]. JOURNAL OF CHROMATOGRAPHY, 1979, 186 (DEC): : 419 - 434
  • [4] THERMODYNAMIC MODEL FOR REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY
    STRANAHAN, JJ
    DEMING, SN
    [J]. ANALYTICAL CHEMISTRY, 1982, 54 (13) : 2251 - 2256
  • [5] MILDIOMYCIN RESIDUE ANALYSIS BY ION-PAIR REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY WITH FLUOROMETRIC DETECTION
    INOUE, M
    HAGIMOTO, T
    [J]. JOURNAL OF PESTICIDE SCIENCE, 1983, 8 (03): : 321 - 326
  • [6] REVERSED-PHASE LIQUID-CHROMATOGRAPHY OF BASIC DRUGS AND PESTICIDES WITH A FLUORIGENIC ION-PAIR EXTRACTION DETECTOR
    VANBUUREN, C
    LAWRENCE, JF
    BRINKMAN, UAT
    HONIGBERG, IL
    FREI, RW
    [J]. ANALYTICAL CHEMISTRY, 1980, 52 (04) : 700 - 704
  • [7] MEASUREMENT OF ANTICONVULSANTS IN SERUM BY REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY
    CHRISTOFIDES, JA
    FRY, DE
    [J]. CLINICAL CHEMISTRY, 1980, 26 (03) : 499 - 501
  • [8] REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY OF GLUCURONIDES - RETENTION AND SELECTIVITY
    STEFANSSON, M
    WESTERLUND, D
    [J]. JOURNAL OF CHROMATOGRAPHY, 1990, 499 : 411 - 421
  • [9] ANALYSIS OF WARFARIN AND ITS METABOLITES BY REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY WITH FLUORESCENCE DETECTION
    WONG, YWJ
    DAVIS, PJ
    [J]. JOURNAL OF CHROMATOGRAPHY, 1989, 469 : 281 - 291
  • [10] SEPARATION OF AQUEOUS POLYTHIONATES BY REVERSED-PHASE ION-PAIR LIQUID-CHROMATOGRAPHY WITH SUPPRESSOR CONDUCTIVITY DETECTION
    ZOU, HF
    JIA, ZJ
    ZHANG, YK
    LU, PC
    [J]. ANALYTICA CHIMICA ACTA, 1993, 284 (01) : 59 - 65
12345