RING-OPENING REACTIONS OF OXABICYCLIC COMPOUNDS AS A ROUTE TO CYCLIC AND ACYCLIC COMPOUNDS WITH MULTIPLE STEREOCENTERS

被引：134
|
作者：
LAUTENS, M
机构：
[1] Department of Chemistry, University of Toronto, Toronto, M5S 1A1, ON
来源：
SYNLETT | 1993年 / 03期
关键词：
D O I：
10.1055/s-1993-22393
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The ring opening of oxabicyclic compounds with a variety of nucleophiles can serve as a useful reaction for the synthesis of cyclic and acyclic compounds with multiple stereocenters. Highly regio- and stereoselective reactions have been observed with organocuprates, silylcuprates, organolithium reagents and organomagnesium compounds.
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页码：177 / 185
页数：9
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