STRUCTURE AND CRYSTALLIZATION KINETICS OF POLY(L-LACTIC ACID)

被引:0
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作者
MAREGA, C
MARIGO, A
DINOTO, V
ZANNETTI, R
MARTORANA, A
PAGANETTO, G
机构
[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,VIA LOREDAN 4,I-35131 PADUA,ITALY
[2] UNIV PALERMO,DIPARTIMENTO CHIM INORGAN,I-90134 PALERMO,ITALY
[3] HIMONT ITALIA SPA,CTR RIC GIULIO NATTA,FERRARA,ITALY
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A structural investigation is described of poly(L-lactic acid) by best fitting of powder X-ray diffraction patterns. The examined sample shows the already known pseudo-orthorhombic alpha-form, and it was possible to determine the location of the two 10(3) polymeric helices in the unit cell and the size distribution of the crystallites. Furthermore, a study is reported of the crystallization kinetics of the above cited polymer by light depolarization measurements in an optical microscope. The crystallization kinetic constants in bulk were evaluated in a temperature range (70-165-degrees-C) wider than that previously resulting from measurements of radial growth of spherulites.
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页码:1599 / 1606
页数:8
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