OLEFINS BY TRANSITION-METAL CATALYZED ELIMINATION-REACTIONS FROM TERTIARY ALCOHOLS AND ACETATES

被引：4
|
作者：
SCHMIDT, T
机构：
[1] Max-Planck-Institut für Kohlenforschung, D-4330 Mülheim an der Ruhr 1
来源：
TETRAHEDRON | 1991年 / 47卷 / 38期
关键词：
CATALYTIC ELIMINATION; OLEFIN FORMATION; MOLYBDENUM CATALYSTS; REGIOSELECTIVITY; ALPHA-CEDRENE AND BETA-CEDRENE;
D O I：
10.1016/S0040-4020(01)91010-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The elimination reaction of water or acetic acid from tertiary alcohols and acetates is catalyzed by transition metal complexes. Olefins are obtained in high yields with catalyst dependent regioselectivity. beta-Cedrene 6b can be prepared as major product from cedryl acetate 5.
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页码：8155 / 8160
页数：6
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