MONTMORILLONITE-SALT INTERACTIONS AT 550-DEGREES-C

被引:4
|
作者
NATALE, IM
HELMY, AK
机构
[1] Universidad Nacional del Sur
[2] Investigadora Comisión de Investigaciones Cientificas de la Provincia de Buenos Aires, Departamento de Agronomía, Universidad Nacional del Sur
关键词
CARBONATES; HYDROXIDES; MONTMORILLONITE; SOLID-STATE REACTION;
D O I
10.1346/CCMN.1992.0400210
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reactions between montmorillonite and carbonates and hydroxides of Na, K and Li were studied at 550-degrees-C as a function of salt content and time. The reactions were found to be rapid with a half-time of 20-30 minutes. Good agreement was obtained between theoretical and experimental stoichiometric values for the clay-carbonate reaction. The 001 and 02,11 reflections of the products of the clay-salt reactions diminished in intensity and/or disappeared at and above the stoichiometric concentrations of the reactants.
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页码:206 / 211
页数:6
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