REACTIONS OF TRANSITION-METAL CARBONYLS WITH ANHYDROUS HF

被引：11

作者：

BREWER, SA ^{[1
]}

HOLLOWAY, JH ^{[1
]}

HOPE, EG ^{[1
]}

机构：

[1] UNIV LEICESTER, DEPT CHEM, LEICESTER LE1 7RH, LEICS, ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 70卷 / 02期

关键词：

TRANSITION-METAL CARBONYLS; ANHYDROUS HF; NMR SPECTROSCOPY; CHARACTERIZATION; REACTIONS;

D O I：

10.1016/0022-1139(94)03112-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of a wide range of transition-metal carbonyls with anhydrous HF are described. In particular, Ru-3(CO)(12), Os-3(CO)(12) and Ir-4(CO)(12) give the solution stable [Ru-3(CO)(12)H](+), [Ru(CO)(5)H](+), [Os-3(CO)(12)H](+), [Os(CO)(5)H](+) and [Ir-4(CO)(12)H-2](2+) respectively, which have been characterised by a combination of H-1 and C-13 NMR spectroscopy.

引用

页码：167 / 169

页数：3

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