THE EFFECTS OF ALCOHOL WITH DIFFERENT CHAIN-LENGTH ON THE PHASE-EQUILIBRIA OF NONIONIC SURFACTANT SYSTEM

被引:7
|
作者
YANG, J
GUO, R
FRIBERG, SE
机构
[1] CLARKSON UNIV,CTR ADV MAT PROC,POTSDAM,NY 13699
[2] YANGZHOU UNIV,TEACHERS COLL,DEPT CHEM,YANGZHOU 225002,PEOPLES R CHINA
关键词
D O I
10.1080/01932699508943677
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Addition of alcohol with longer chain length (C6H13OH, C8H17OH, and C12H21OH) caused a reduction the cloud point of a commercial nonionic surfactant, Tesgitol (T-15-s-9). The formation of lamellar liquid crystal (LLC) was favored so that isotropic liquid (L(1))-LLC two-phase region became wider with increasing temperature at an appropriate weight ratio of surfactant to alcohol. The isotropic liquid phase/liquid two phase transformation was replaced by a two-phase transformation to isotropic liquid/lamellar liquid crystal at the cloud point for the system without alcohol.
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页码:249 / 261
页数:13
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