DIELS-ALDER REACTIONS OF PHOSPHAALKENE AND PHOSPHADIENE COMPLEXES

被引：0
|
作者：
TRAUNER, H
DELACUESTA, E
MARINETTI, A
MATHEY, F
机构：
[1] ECOLE POLYTECH,DCPH,HETEROELEMENTS & COORDINAT LAB,CNRS,URA 1499,F-91128 PALAISEAU,FRANCE
[2] UNIV COMPLUTENSE MADRID,FAC FARM,DEPT QUIM ORGAN & FARMACEUT,E-28040 MADRID,SPAIN
来源：
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE | 1995年 / 132卷 / 04期
关键词：
PHOSPHAALKENE COMPLEXES; 1-PHOSPHA-1,3-DIENE COMPLEXES; 4+2] CYCLOADDITION; 1,2-DIHYDROPHOSPHETE; PHOSPHININE;
D O I：
暂无
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Electron-rich dienes are well suited to cycloaddition reactions with unstable phosphaalkene-Mo(CO)(5) complexes. The chemical properties of the resulting adducts have been examined briefly. (1-Phospha-1,3-diene)Mo(CO)(5) complexes are generated transiently from the corresponding 1,2-dihydrophosphetes and reacted with various dienophiles in Diels-Alder-like reactions. The above cycloadditions offer a general approach to dihydro- or tetrahydrophosphinines which are intermediates in the synthesis of new phosphinine derivatives.
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页码：384 / 393
页数：10
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