SYNTHESIS AND CATALYTIC ACTIVITY OF BINUCLEAR COBALT(II) AND NICKEL(II) COMPLEXES

被引：9

作者：

SRINIVAS, B ^{[1
]}

ZACHARIAS, PS ^{[1
]}

机构：

[1] UNIV HYDERABAD,SCH CHEM,HYDERABAD 500134,ANDHRA PRADESH,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1991年 / 16卷 / 05期

关键词：

D O I：

10.1007/BF01024322

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Binuclear Ni(II) and Co(II) complexes derived from 2,6-diformyl-4-methylphenol and various aromatic monoamines have been prepared and investigated. The Ni(II) complexes have Ni2LCl3 composition while the Co(II) complexes have Co2L2Cl2 composition, where L represents the organic ligand. The complexes are active catalysts in the oxidation of 3,5-di-t-butylcatechol (3,5-DTBC) by dioxygen, but less so than their Cu analogues. This result is attributed to the absence of antiferromagnetic coupling between the metal centres.

引用

页码：521 / 523

页数：3

共 50 条

[1] Synthesis and Catalytic Activity of Nickel(II) and Cobalt(II) Complexes Involving Chiral Leucinol
Luo Mei
Zhang Zhi-Jun
Wang Lei
Zhang Jing-Cheng
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (12) : 1851 - 1856
[2] Synthesis, crystal structure, spectral properties and catalytic activity of binuclear copper(II), mononuclear nickel(II) and cobalt(III) complexes containing Schiff base ligand
Pattanayak, Poulami
Pratihar, Jahar Lal
Patra, Debprasad
Brandao, Paula
Felix, Vitor
INORGANICA CHIMICA ACTA, 2014, 418 : 171 - 179
[3] KINETICS AND MECHANISM OF LIGAND SUBSTITUTION IN BINUCLEAR NICKEL(II) AND COBALT(II) COMPLEXES
HYNES, MJ
DOODY, MT
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1995, 27 (05) : 419 - 429
[4] Synthesis of heterometallic binuclear cobalt(II) phthalocyanines and their catalytic activity in the oxidation of a mercaptan
Makarov, Sergey G.
Ketkov, Sergey Yu.
Grishin, Ivan D.
Woehrle, Dieter
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2023, 27 (01) : 694 - 701
[5] Binuclear cobalt(II), nickel(II), copper(II) and palladium(II) complexes of a new Schiff-base as ligand: Synthesis, structural characterization, and antibacterial activity
Geeta, B.
Shravankumar, K.
Reddy, P. Muralidhar
Ravikrishna, E.
Sarangapani, M.
Reddy, K. Krishna
Ravinder, V.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2010, 77 (04) : 911 - 915
[6] COORDINATION-COMPOUNDS AS LIGANDS - BINUCLEAR COPPER(II), NICKEL(II) AND COBALT(II) COMPLEXES
PODDAR, SN
KUNDU, BC
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1984, 23 (06): : 488 - 492
[7] Synthesis and magnetism of μ-tetracarboxylato binuclear nickel(II) complexes
Li, YT
Yan, CW
Xu, CS
Liao, DZ
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1998, 28 (03): : 367 - 381
[8] PENTACOORDINATED BINUCLEAR COMPLEXES OF COBALT(II) AND NICKEL(II) WITH 3-IMIDAZOLINE NITROXIDES
LAUGIER, J
OVCHARENKO, V
REY, P
INORGANICA CHIMICA ACTA, 1995, 236 (1-2) : 49 - 53
[9] Synthesis, characterization, and biological activity of cobalt(II), nickel(II), copper(II), and zinc(II) complexes of secnidazole
Betanzos-Lara, Soledad
Gracia-Mora, Isabel
Granada-Macias, Pilar
Flores-Alamo, Marcos
Barba-Behrens, Norah
INORGANICA CHIMICA ACTA, 2013, 397 : 94 - 100
[10] Metalloantibiotics: Synthesis and antibacterial activity of cobalt(II), copper(II), nickel(II) and zinc(II) complexes of kefzol
Chohan, ZH
Supuran, CT
Scozzafava, A
JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 2004, 19 (01) : 79 - 84

← 1 2 3 4 5 →