TRANSITION-METALS COMPLEXED TO ORDERED MESOPHASES .8. CYCLOPALLADATED PARA-AZOXYANISOLE COMPLEXES - CRYSTAL-STRUCTURE OF [N-(PHENYL)-2-SALICYLIDENEAMINATO][4'-(METHOXYPHENYL-NNO-AZOXY-N2)-4-METHOXYPHENYL-2-ATO]PALLADIUM(II)

被引：28

作者：

GHEDINI, M

MORRONE, S

DEMUNNO, G

CRISPINI, A

机构：

[1] Dipartimento di Chimica, Universitá della Calabria, I-87036 Arcavacata, Cs

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 415卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80126-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of the cyclopalladated p-azoxyanisole chloro-bridged dimer [Pd(Azoxy)Cl]2, 1, is reported and its reactions with some salicylideneaniline derivatives (HL1-5) are described. H-1 NMR spectral observations indicate that except for [Pd(Azoxy)(L4)] the mononuclear [Pd(Azoxy)(L)] products are ca 5:1 mixtures of N-trans and N-cis isomers. In the HL4 case (HL4 = salicylidene(2,4-dimethyl)aniline) the only product which was detected is the N-trans isomer. The crystal structure of trans-[Pd(Azoxy)(L1)] (HL1 = salicylideneaniline) (3-trans) is monoclinic.

引用

页码：281 / 291

页数：11

共 14 条

[1] CYCLOPALLADATED P-AZOXYANISOLE COMPLEXES - SYNTHESIS AND STRUCTURE OF ([BIS(2-PHENYLPYRIDINE)]-[4'-(METHOXYPHENYL-NNO-AZOXY-N2)-4-METHOXYPHENYL-2-ATO]-PALLADIUM(II))(TETRAFLUOROBORATE)
ARMENTANO, S
DEMUNNO, G
GHEDINI, M
MORRONE, S
INORGANICA CHIMICA ACTA, 1994, 218 (1-2) : 211 - 213
[2] TRANSITION-METALS COMPLEXED TO ORDERED MESOPHASES - SYNTHESIS AND CRYSTAL-STRUCTURE OF (8-HYDROXYQUINOLINATO)[2-(4'-METHOXYPHENYLAZO-N-2)-5-METHOXYPHENYL]PALLADIUM(II)
LANFREDI, AMM
UGOZZOLI, F
GHEDINI, M
LICOCCIA, S
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 86 (03): : 165 - 168
[3] TRANSITION-METALS COMPLEXED TO ORDERED MESOPHASES .1. SYNTHESIS CHARACTERIZATION AND MESOMORPHIC PROPERTIES OF BINUCLEAR CYCLOPALLADATED PHENYLPYRIMIDINE SPECIES - CRYSTAL-STRUCTURE OF BIS((5-(1-HEXYL)-2-[(4'-METHOXY)PHENYL-2'-ATO]PYRIMIDINE-N',C2')-MU-ACETATO)DIPALLADUM(II)
GHEDINI, M
PUCCI, D
DEMUNNO, G
VITERBO, D
NEVE, F
ARMENTANO, S
CHEMISTRY OF MATERIALS, 1991, 3 (01) : 65 - 72
[4] TRANSITION-METALS COMPLEXED TO ORDERED MESOPHASES .6. SYNTHESIS, MESOMORPHIC BEHAVIOR AND X-RAY MOLECULAR-STRUCTURE OF THE CYCLOPALLADATED DIMER [(L)PDCL]2 (HL=N-(4-METHOXYBENZYLIDENE)-4'-BUTYLANILINE)
GHEDINI, M
ARMENTANO, S
DEMUNNO, G
CRISPINI, A
NEVE, F
LIQUID CRYSTALS, 1990, 8 (05) : 739 - 744
[5] STRUCTURE OF CRYSTALLINE PREDECESSORS OF MESOPHASES - X-RAY-INVESTIGATION AND ENERGY CALCULATION OF BIS[4-NORMAL-HEPTYLOXY)-N-(PARA-METHOXYPHENYL)BENZALDIMINO-2-OLATE] COPPER(2+) CRYSTAL
POLISHCHUK, AP
ANTIPIN, MY
TIMOFEEVA, TB
STRUCHKOV, YT
GALYAMETDINOV, YG
OVCHINNIKOV, IV
KRISTALLOGRAFIYA, 1986, 31 (03): : 466 - 473
[6] Crystal structure of [2-(4-methoxyphenyl)pyrazine-κ2C,N) chlorido[N,N′-bis-(2,6-diisopropyl-phenyl)imidazol-2-ylidene-κC)] palladium(II), C38H45ClN4OPd
Wang, Xin-Ling
Li, Hong-Mei
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2016, 231 (01): : 145 - 147
[7] THE CRYSTAL AND MOLECULAR-STRUCTURE OF 4-OXO-3H-2[N-(PARA-METHOXYPHENYL)IMINIUM]6-METHYL-8-(PARA-METHOXYPHENYL)IMIDAZO[1,2-A]-1,3,5-TRIAZINE TRIFLUOROACETATE
UDUPA, MR
KREBS, B
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1982, 158 (1-2): : 149 - 157
[8] METAL-COMPLEXES WITH MIXED-LIGANDS .8. CRYSTAL-STRUCTURE OF DIPERCHLORATO-TETRAIMIDAZOLO-COPPER(II)-CU(C3H4N2)4(CLO4)2
IVARSSON, G
ACTA CHEMICA SCANDINAVICA, 1973, 27 (09): : 3523 - 3530
[9] ASYMMETRIC-SYNTHESIS OF COMPLEXED CYCLIC N,O-ACETALS BY USE OF PLATINUM(II) COMPLEXES - CRYSTAL-STRUCTURE OF TRANS-[PTCL2(C2H4)(2-PARA-NO2C6H4(CHNH(CH2)3O-))]
ALBINATI, A
ARZ, C
PREGOSIN, PS
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (01) : C18 - C20
[10] STRUCTURE OF COMPLEXES OF THE TRANSITION-METALS WITH PARAMAGNETIC LIGANDS .4. CRYSTAL AND MOLECULAR-STRUCTURE OF THE PYRIDINE ADDUCT OF BIS-(2,2,5,5-TETRAMETHYLPYRROLIDINE-1-OXYL-3-N-2-OXY-5-BROMO-SALICYLIDENEIMINATO)COPPER(II)
RODIN, NP
MEDZHIDOV, AA
KUTOVAYA, TM
GUSEINOVA, MK
JOURNAL OF STRUCTURAL CHEMISTRY, 1981, 22 (01) : 63 - 66

← 1 2 →