SOLID-SOLUTIONS OF BISMUTH OXIDE AS PROMISING CATALYSTS FOR OXIDATIVE COUPLING OF METHANE

被引：0

作者：

VOSKRESENSKAYA, EN ^{[1
]}

KURTEEVA, LI ^{[1
]}

ANSHITS, AG ^{[1
]}

机构：

[1] KRASNOYARSK CHEM NAT ORGAN MAT INST,K MARX STR 42,KRASNOYARSK 660049,USSR

来源：

APPLIED CATALYSIS A-GENERAL | 1992年 / 90卷 / 02期

关键词：

BISMUTH OXIDE; ERBIUM DOPED BISMUTH OXIDE; LATTICE OXYGEN DEFECTS; LITHIUM; METHANE OXIDATIVE COUPLING; SAMARIUM; SOLID SOLUTIONS;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The relationship between the catalytic properties for Li/Bi2O3, Sm/Bi2O3, Er/Bi2O3 systems in oxidative coupling of methane (OCM) and their oxygen defect type has been investigated. It has been shown that solid solutions in Li/Bi2O3 system are active and selective catalysts, while defects of the type of hole centres probably determine their properties. Er/Bi2O3, Sm/Bi2O3 oxygen ion conductors, having a high mobility of lattice oxygen and a significant concentration of oxygen vacancies, are active but show much less selectivity in the OCM reaction.

引用

页码：209 / 216

页数：8

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