LIQUID-LIQUID-EXTRACTION AND SEPARATION OF LANTHANUM(III)

被引:2
|
作者
LANGADE, AD [1 ]
SHINDE, VM [1 ]
机构
[1] SHIVAJI UNIV,DEPT CHEM,ANALYT LAB,KOLHAPUR 416004,MAHARASHTRA,INDIA
关键词
EXTRACTIVE METALLURGY - SEPARATION;
D O I
10.1246/bcsj.54.600
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Separation of lanthanum(III) from iron(III), molybdenum(VI), vanadium(V), chromium(VI), titanium(IV), bismuth(III), zirconium(IV), scandium(III), uranium(VI), and beryllium is achieved by solvent extraction with mesityl oxide from sodium salicylate solution (0. 1 M adjusted to pH 7). Lanthanum from the organic phase is stripped with water and determined photometrically as its arsenazo complex at 570 nm. The extracted species is trisolvated i. e. La(HOC//6H//4COO)//3 multiplied by (times) 3MeO. The results of separation are reported.
引用
收藏
页码:600 / 603
页数:4
相关论文
共 50 条
  • [1] LIQUID-LIQUID-EXTRACTION OF AM/III
    MATHUR, JN
    KHOPKAR, PK
    [J]. RADIOCHEMICAL AND RADIOANALYTICAL LETTERS, 1983, 57 (5-6): : 259 - 271
  • [2] SEPARATION OF PRECIOUS METALS BY LIQUID-LIQUID-EXTRACTION
    GLOE, K
    MUHL, P
    BEGER, J
    [J]. ZEITSCHRIFT FUR CHEMIE, 1983, 23 (02): : 71 - 71
  • [3] LIQUID-LIQUID-EXTRACTION OF CERIUM(III) AND LANTHANUM(III) FROM AQUEOUS CHLORIDE SOLUTIONS BY SME-529
    URBANSKI, TS
    ABBRUZZESE, C
    FORNARI, P
    MASSIDDA, R
    [J]. HYDROMETALLURGY, 1992, 28 (01) : 1 - 12
  • [4] LIQUID-LIQUID-EXTRACTION SEPARATION AND DETERMINATION OF PLUTONIUM AND AMERICIUM
    BERNABEE, RP
    PERCIVAL, DR
    HINDMAN, FD
    [J]. ANALYTICAL CHEMISTRY, 1980, 52 (14) : 2351 - 2353
  • [5] LIQUID-LIQUID-EXTRACTION AND SEPARATION OF LANTHANUM(III) FROM TITANIUM(IV), ZIRCONIUM(IV), HAFNIUM(IV), THORIUM(IV) AND URANIUM(VI)
    BHILARE, NG
    SHINDE, VM
    [J]. ANALYST, 1995, 120 (02) : 391 - 393
  • [6] LIQUID-LIQUID-EXTRACTION AND SEPARATION STUDIES OF URANIUM(VI)
    LANGADE, AD
    SHINDE, VM
    [J]. MIKROCHIMICA ACTA, 1980, 2 (1-2) : 93 - 98
  • [7] FACILE SEPARATION OF SULFONAMIDES FROM THEIR DEGRADATES BY LIQUID-LIQUID-EXTRACTION
    FINK, DW
    MARTIN, RP
    BLODINGER, J
    [J]. JOURNAL OF PHARMACEUTICAL SCIENCES, 1978, 67 (10) : 1415 - 1419
  • [8] LIQUID-LIQUID-EXTRACTION OF INDIUM(III) FROM SALICYLATE SOLUTION
    MUDSHINGIKAR, VV
    SHINDE, VM
    [J]. FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1984, 318 (08): : 612 - 612
  • [9] SEPARATION OF METALS BY COMPLEXING VIA LIQUID-LIQUID-EXTRACTION PROCEDURES
    KATZIN, LI
    MASON, GW
    PEPPARD, DF
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, 172 (SEP3): : 72 - 72
  • [10] SEPARATION AND ENRICHMENT OF CHROMIUM(III) TRACES FROM A MOLYBDENUM MATRIX BY MEANS OF LIQUID-LIQUID-EXTRACTION FOLLOWED BY LIQUID-SOLID SEPARATION
    LANKMAYR, EP
    MULLER, K
    [J]. RADIOCHEMICAL AND RADIOANALYTICAL LETTERS, 1975, 22 (01): : 63 - 70