SULFONIC HYDRAZIDE FIXATION TO TRINUCLEAR RUTHENIUM CLUSTERS - SYNTHESIS AND STRUCTURE OF (MU-2-H)RU3(CO)9[MU-3-ETA-2-N2N-NSO(O)2MES]

被引：0

作者：

RHEINWALD, G ^{[1
]}

STOECKLIEVANS, H ^{[1
]}

SUSSFINK, G ^{[1
]}

机构：

[1] UNIV NEUCHATEL,INST CHIM,AVE BELLEVAUX 51,CH-2000 NEUCHATEL,SWITZERLAND

来源：

CHIMIA | 1993年 / 47卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sulfonic hydrazides were found to react thermally with Ru3(CO)12 without cleavage of the N-N bond resulting in the formation of trinuclear hydrazido clusters. The X-ray structure analysis of the derivative (mu-H)RU3(CO)9[mu3-eta2-H2NNS(O)2Mes] shows a triangular Ru3 framework capped by an intact N-N unit.

引用

页码：196 / 198

页数：3

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