ADDITION OF TETRACHLOROMETHANE TO ALKENES CATALYZED BY COBALT(II) AMINE COMPLEX

被引：13
|
作者：
KOTORA, M [1 ]
ADAMEK, F [1 ]
HAJEK, M [1 ]
机构：
[1] CZECHOSLOVAK ACAD SCI, INST CHEM PROC FUNDAMENTALS, ROZVOJOVA 135, CS-16502 PRAGUE 6, CZECHOSLOVAKIA
来源：
CATALYSIS LETTERS | 1993年 / 18卷 / 04期
关键词：
ADDITION REACTIONS; COBALT(II) CATALYST; FREE RADICALS;
D O I：
10.1007/BF00765280
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The cobalt(II)-2-methylpropylamine complex is an efficient catalyst for addition of tetrachloromethane to alkenes under mild reaction conditions (80-degrees-C) providing 1 : 1 adducts up to 99.5% yield. Reactions with vinyl monomers provided low yield of 1 : 1 addition products (5-48%) presumably due to radical chain processes favoring telomerization and polymerization.
引用
收藏
页码：345 / 348
页数：4
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