1,4-Diazabicyclo[2.2.2]octane-1,4-diium bis(3-chlorobenzoate)

被引：2
|
作者：
Yao, Zi-Shuo [1 ]
Sato, Osamu [1 ]
机构：
[1] Kyushu Univ, Inst Mat Chem & Engn, 6-1,Kasugakoen, Fukuoka 8168580, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
data-to-parameter ratio = 14.5; mean σ(C-C) = 0.003 Å; R factor = 0.037; single-crystal X-ray study; T = 123 K; wR factor = 0.097;
D O I：
10.1107/S1600536814000610
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
-In the title salt C6H14N22+center dot 2C(7)H(4)ClO(2-), two 3-chlorobenzoate (3CBA) anions are bridged by one diprotonated 1,4-diaza-bicyclo[2.2.2] octane-1,4-diium (H(2)DABCO(2+)) dication through N-H center dot center dot center dot O hydrogen bonds. In this way, a trimeric unit is generated, in which the mean planes of the two 3CBA anions are twisted with respect to each other by a dihedral angle of 59.87 (9)degrees. The trimeric units are linked into a three-dimensional network via weak C-H center dot center dot center dot O interactions.
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收藏
页码：0154 / +
页数：8
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