ACETYLENE FROM BENZENE - A NOVEL AND SELECTIVE MICROWAVE-ASSISTED CRACKING SYNTHESIS

被引:12
|
作者
BAMWENDA, G [1 ]
DEPEW, MC [1 ]
WAN, JKS [1 ]
机构
[1] QUEENS UNIV,DEPT CHEM,KINGSTON K7L 3N6,ONTARIO,CANADA
关键词
D O I
10.1163/156856793X00479
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel and efficient process for the cracking of benzene to acetylene with over 90% selectivity is described. The reactions are induced by a pulsed microwave technology over alumina and silica supported Nickel catalysts.
引用
收藏
页码:553 / 564
页数:12
相关论文
共 50 条
  • [1] Microwave-assisted synthesis of novel purine nucleosides as selective cholinesterase inhibitors
    Schwarz, S.
    Csuk, R.
    Rauter, A. P.
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 12 (15) : 2446 - 2456
  • [2] Microwave-assisted Synthesis of Anilinocarbonyl Acetylene: A Quick Access to Terminal Alkynes
    Jiang, Yubo
    Han, Chunmei
    Liang, Xueqiu
    [J]. ADVANCES IN APPLIED SCIENCES AND MANUFACTURING, PTS 1 AND 2, 2014, 850-851 : 66 - +
  • [3] Development of Au/C catalysts by the microwave-assisted method for the selective hydrochlorination of acetylene
    Wittanadecha, W.
    Laosiripojana, N.
    Ketcong, A.
    Ningnuek, N.
    Praserthdam, P.
    Monnier, J. R.
    Assabumrungrat, S.
    [J]. REACTION KINETICS MECHANISMS AND CATALYSIS, 2014, 112 (01) : 189 - 198
  • [4] Development of Au/C catalysts by the microwave-assisted method for the selective hydrochlorination of acetylene
    W. Wittanadecha
    N. Laosiripojana
    A. Ketcong
    N. Ningnuek
    P. Praserthdam
    J. R. Monnier
    S. Assabumrungrat
    [J]. Reaction Kinetics, Mechanisms and Catalysis, 2014, 112 : 189 - 198
  • [5] Microwave-assisted synthesis of novel ferrocenyl pyrrolizidines
    Zhang Yu-Mei
    Liu Peng
    Zhang Hong-Li
    Feng Guo-Liang
    Geng Li-Jun
    [J]. JOURNAL OF CHEMICAL RESEARCH, 2012, (09) : 536 - 538
  • [6] MICROWAVE-ASSISTED SYNTHESIS
    Gediz Erturk, Aliye
    Bekdemir, Yunus
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2014, 189 (02) : 285 - 292
  • [7] Microwave-assisted synthesis of 1,4-bis(difluoromethyl)benzene
    Dong-Hui Pan
    Tong-Zhen Wang
    Guo-Min Xiao
    [J]. Chemical Papers, 2017, 71 : 1249 - 1254
  • [8] Rapid microwave-assisted synthesis of benzene bridged periodic mesoporous organosilicas
    Smeulders, Geert
    Meynen, Vera
    Van Baelen, Gitte
    Mertens, Myrjam
    Lebedev, Oleg I.
    Van Tendeloo, Gustaaf
    Maes, Bert U. W.
    Cool, Pegie
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (19) : 3042 - 3048
  • [9] Microwave-assisted synthesis of 1,4-bis(difluoromethyl)benzene
    Pan, Dong-Hui
    Wang, Tong-Zhen
    Xiao, Guo-Min
    [J]. CHEMICAL PAPERS, 2017, 71 (07) : 1249 - 1254
  • [10] Synthesis and magnetic properties of aligned carbon nanotubes by microwave-assisted pyrolysis of acetylene
    Fu, Dongju
    Ma, Qing
    Zeng, Xierong
    Chen, Jianjun
    Zhang, Weili
    Li, Dongshuang
    [J]. PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2013, 54 : 185 - 190